Non-precious metal sulfide energy storage materials
Non-precious metal sulfide energy storage materials
The article provides an overview of recent research and significant advances reported in the literature, covering from synthesis to properties and to applications especially in energy conversion and storage, such as lithium-ion batteries, solar cells, fuel cells and piezoelectric nanogenerators.
Hybrid energy storage device from binder-free zinc-cobalt sulfide
Transition metal sulfides are highly promising for their remarkable electrochemical activity together with low electronegativity for energy storage applications [2]. Small band gap
MOFs-derived transition metal sulfide composites for
Energy Storage Materials. Volume 41, October 2021, Pages 404-426. MOFs-derived transition metal sulfide composites for advanced sodium ion batteries. Author links open overlay panel It is a real-life technique with the non-destruction of the electrode material and can directly obtain the information about the topography evolution and the
Synergistic Modulation of Non-Precious-Metal
ConspectusHydrogen is an ideal energy carrier and plays a critical role in the future energy transition. Distinct from steam reforming, electrochemical water splitting, especially powered by renewables, has been considered as a
Recent progress and emerging challenges of transition metal
In this context, special emphasis is placed on nickel, cobalt, molybdenum, tin, manganese, and tungsten metal sulfides and their composites as advanced electrode materials for supercapacitor applications. Finally, the benefits and challenges of using transition metal sulfide-based electrode materials for future clean energy storage are discussed.
Recent development in electrocatalysts for hydrogen
Hydrogen is a carbon-free alternative energy source for use in future energy frameworks with the advantages of environment-friendliness and high energ
Nanostructured metal sulfides for energy storage
Herein, we summarize recent advances in nanostructured metal sulfides, such as iron sulfides, copper sulfides, cobalt sulfides, nickel sulfides, manganese sulfides, molybdenum sulfides, tin sulfides, with zero-, one-, two-, and three
Transition metal oxides and transition metal sulfides as
Pre-intercalation is a process that involves engineering the interface between electrode materials and carriers to enhance diffusion kinetics in energy storage systems. This method is effective at stabilizing the structure, shielding the electrostatic interaction between carriers and electrode materials, and increasing the ionic conductivity
Metal sulfide nanostructures : synthesis,
The amorphous molybdenum sulfide films are among the most active non-precious catalysts for hydrogen evolution reactions. 77c With the unique characteristics of nanostructured materials, metal sulfide
Metal-based mesoporous frameworks as high-performance
Additionally, the paper showcases a range of high-performance applications of these materials in the arena of energy storage and conversion. Finally, the review concludes by summarizing the current status and offering insights into future application prospects of metal-based mesoporous materials within the domain of energy storage and conversion.
Low-temperature ammonia decomposition catalysts for
Provides a comprehensive outlook of development of precious and non-precious metal catalyst for ammonia decomposition. Its volatility and low volumetric energy density makes the storage and transportation of hydrogen, or a reagent from which it can be generated, a grand challenge. In early 2001, Schlapbach et al. published a review on
P-doped MOF-derived CoNi bimetallic sulfide
Therefore, it is urgent to find a non-precious metal-based catalyst with abundant natural resources, low cost and high catalytic stability. Recently, transition metal sulfides (TMSs) have attracted much attention as important electrocatalytic materials for water splitting due to their reasonable design, high activity and easy synthesis [13
Challenges and prospects of metal sulfide materials for supercapacitors
Insights into charge storage and electroactivation of mixed metal sulfides in alkaline media: NiCoMn ternary metal sulfide nano-needles forming core–shell structures for hybrid
Recent Advances in Non-Precious Metal–Nitrogen–Carbon
Electrochemical Energy Reviews, 2022, 5(4): 11-. Yiqun Chen, Junru Zhang, Lijun Yang, Xizhang Wang, Qiang Wu, Zheng Hu. Recent Advances in Non-Precious Metal–Nitrogen–Carbon Single-Site Catalysts for CO 2 Electroreduction Reaction to CO[J
Review on recent advances in nanostructured transition-metal-sulfide
Recent developments demonstrated that transition metal sulfides (TMSs) have emerged as a promising class of materials for ASCs due to their low cost, fascinating redox
Copper Indium Sulfide Enables Li-CO2 Batteries with
High energy density Li-CO 2 batteries have attracted much attention owing to the "two birds with one stone" feature in fixing greenhouse gas CO 2 and providing renewable energy. However, poor reversibility of the discharge product Li 2 CO 3 is one of the main problems that limit its application, resulting in poor cycling stability and severe polarization. . Herein, copper indium
Strong electron coupling effect of non-precious metal
Engineering of non-precious metal nanomaterials as cocatalysts can play a significant role in low-cost, sustainable, and large-scale photocatalytic hydrogen production. Herein, MnCdS-Vs/NiCo 2 S 4 (MCSN) Schottky junction nanomaterials with strong electron coupling effect were prepared by a two-step hydrothermal method and successfully applied
Non-precious transition metals as counter electrode of
Energy Storage Materials. Volume 7, April 2017, perovskite solar cells employ gold or silver as counter electrode materials. The use of the precious metals is a serious obstacle to the practical application of perovskite solar cells. In this work, low-cost non-precious transition metals are investigated to replace gold or silver as counter
Metal sulfide nanostructures : synthesis, properties and
Controlled synthesis of high-entropy materials offers a unique platform to explore unprecedented electrochemical properties. High-entropy metal sulfides (HEMSs) have recently emerged as promising electrodes in
Applications of transition-metal sulfides in the cathodes of
Lithium–sulfur (Li–S) batteries are considered as one of the most promising candidates for next-generation energy storage systems with high energy density and reliable performance. However, the commercial applications of lithium–sulfur batteries is hindered by several shortcomings like the poor conductivity of sulfur and its reaction products, and the loss
Recent progress of electrocatalysts for oxygen reduction in
Except for the electrode materials, the reaction circumstance is an essential factor for ORR process [12].For example, the alkaline nature allows the surface-independent transfer of outer electrons during the first stage of ORR [22].The non-specificity of the environment permits the utilization of a variety of nonprecious metal electrocatalysts [23].
Metal-organic framework derived iron-nickel sulfide
Electrochemical water splitting is an important issue for sustainable production of hydrogen for energy storage in recent years [[1], [2] In non-precious metal electrocatalysts, Results showed that metal sulfide improves intrinsic conductivity of electrocatalysts while (oxy)hydroxide on the surface acts as the catalytic site for OER
Electrochemical reduction of nitrate to ammonia using non-precious
Herein, recent developments of non-precious transition metal-based catalysts in electrochemical nitrate reduction and the pertinent mechanisms are described. In addition to the important techniques, future challenges and prospects are discussed to guide future research on non-precious metal catalysts for commercial NH 3 synthesis by NO 3 −
Nitrogen-Doped Nickel Sulfide Composite Array Electrode as
Transition metal sulfides have become some of the most promising non-precious metal catalysts due to their high specific surface area, unique electronic structure, and rich
Recent advances in transition-metal-sulfide-based
Hydrogen produced via water electrolysis can act as an ideal clean chemical fuel with superb gravimetric energy density and high energy conversion efficiency, solving the problems of conventional fossil fuel exhaustion and environmental contamination. Transition metal sulfides (TMS) have been extensively explored as effective, widely available alternatives to precious
Transition-metal sulfides with excellent hydrogen and
The exposure of an abundance of catalytic sites in nanosheet clusters enhances catalytic activity for the hydrogen evolution process. The optimized WS 2 /NiS x composite outperforms most non-precious metal electrocatalysts and demonstrated good catalytic stability with 10 mA/cm 2 of just 72 mV value for overpotential in alkaline conditions [92].
Nanocarbon-based metal-free and non-precious metal
The fossil fuels will be exhausted in the near future, and the need for groundbreaking sustainable energy solutions has been urgent. Electrochemistry-based energy conversion and storage devices with high efficiency, reliability and environmental friendliness (such as metal-air batteries, fuel cells, water splitting, and solar fuel synthesis) have become an important
Metal-organic frameworks: Advances in first-principles
Metal-organic frameworks (MOFs) are a class of three-dimensional porous nanomaterials formed by the connection of metal centers with organic ligands [1].Due to their high specific surface area and tunable pore structures, and the ability to manipulate the chemical and physical properties of such porous materials widely through the substitution of metal nodes
Transition metal nitride-based materials as efficient
As a group of interstitial compounds, transition metal nitrides (TMNs) have attracted considerable interests in energy storage and conversion techniques due to the unique physicochemical properties, especially the resemblance of electronic structure to noble metals [40], [41].To date, more than one hundred TMNs have been developed as electrocatalysts for
Recent advances in non‐precious Ni‐based
The creation of hydrogen and oxygen from water can be a paramount way to produce clean fuel through Earth-abundant and non-precious photoelectrochemical (solar to hydrogen production) and electrocatalysis
Metal-organic frameworks derived porous carbon, metal oxides and metal
The energy storage field has witnessed a dramatic expansion in terms of short charging time of supercapacitors, especially in the highly active electrode materials. Metal-organic frameworks (MOFs) materials have been extensively applied as precursors or templates for the synthesis of carbon, metal oxides/sulfides-based compounds as high
non-precious metal sulfide energy storage materials
Metal sulfide nanostructures : synthesis, properties and applications in energy conversion and storage . Nanostructured metal sulfide materials, such as MoS 2 nanotubes and Bi 2 S 3 nanorods, have attracted much attention for electrochemical hydrogen storage
Recent progress of precious-metal-free electrocatalysts for efficient
Metal-free materials, transition-metal oxides/phosphides/sulfides, and polyoxometalate-based materials, are promising precious-metal-free candidates for efficient water oxidation in acidic media. Here, this emerging research field is reviewed regarding design concepts, key practical issues, and the outlooks for future research directions.
Metal-organic framework derived iron-nickel sulfide
Benefiting from the electrical conductivity of FeNi sulfide and the abundant active sites of in situ generated amorphous FeNiOOH, the as-prepared Fe 0.75 Ni 0.25 S 2 nanorods exhibit a low overpotential of 247 mV with a small Tafel slope of 47.6 mV dec −1 at a current density of 10 mA cm −2 in alkaline media.. Download: Download high-res image (299KB)
Optimizing sodium storage and durability in
Optimizing sodium storage and durability in metal sulfide anodes with a 3D graphene architecture†. Mujtaba Aminu Muhammad ab, Yangjie Liu a, Baffa Haruna c, Ahmed Abdel-aziz ac, Zul Qarnain c, Amir Mahmoud Makin c,
A review on synthesis and modification of cobalt
Therefore, it is very necessary to develop low-cost, high activity, and good stability of non-precious metal catalyst to replace the precious metal catalyst (Pt, RuO 2), and to further reduce overpotential and power consumption. To date, great efforts have been made to develop transition metal compounds with electrocatalytic performance, such
Highly porous non-precious bimetallic
Investigations into non-precious metal catalysts for hydrogen evolution are ongoing. Here, the authors report a hierarchical, nanoporous copper-titanium electrocatalyst, and demonstrate that it
Review on recent advances in nanostructured transition-metal-sulfide
In the past few decades, electrochemical energy storage devices including rechargeable batteries and supercapacitors have attracted significant attention due to their widespread applications in hybrid electric vehicles, smart portable electronics and industrial power and energy management [4], [5], [6] pared to batteries, supercapacitors stand out owing
Rational design of Mo-doped NixSy/Ni2P
The development of highly active and long-lasting multifunctional electrocatalysts is crucial for advancing clean and renewable energy technologies. In this study, we developed a Mo-doped NixSy/Ni2P self
6 FAQs about [Non-precious metal sulfide energy storage materials]
What are high entropy metal sulfides?
Learn more. Controlled synthesis of high-entropy materials offers a unique platform to explore unprecedented electrochemical properties. High-entropy metal sulfides (HEMSs) have recently emerged as promising electrodes in electrochemical energy storage applications.
What are metal sulfide nanomaterials?
Metal sulfide nanomaterials have attracted great attention because of their excellent properties and promising applications in electronic, optical and optoelectronic devices. Well-aligned nanostructure arrays on substrates are highly attractive for their enhanced properties and novel applications.
Are transition metal sulfides suitable for electrocatalytic applications?
Transition metal sulfides have become some of the most promising non-precious metal catalysts due to their high specific surface area, unique electronic structure, and rich phase and property modulation methods. However, defects such as high overpotential and slow reaction kinetics hinder their implementation in electrocatalytic applications.
Are high entropy metal sulfides a promising electrode?
High-entropy metal sulfides (HEMSs) have recently emerged as promising electrodes in electrochemical energy storage applications. However, synthesizing HEMSs with a tunable number of components and composition is still challenging.
Why are metal sulfide nanostructures important?
Metal sulfide nanostructures are important nanomaterials due to their extensively promising applications in electronic, optical, optoelectronic and magnetic devices. The aligned nanostructure arrays on substrates are highly attractive due to their enhanced properties and novel applications.
What are electrochemical energy storage devices?
In the past few decades, electrochemical energy storage devices including rechargeable batteries and supercapacitors have attracted significant attention due to their widespread applications in hybrid electric vehicles, smart portable electronics and industrial power and energy management , , .
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